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Carbadodecaborate Salts - Stable Boron Cluster Anions for Advanced Chemical Applications


Carborane-based compounds have become increasingly important in modern inorganic and organometallic chemistry due to their remarkable thermal and chemical stability. Among them, the carbadodecaborate salts, including Trimethylammonium carbadodecaborate (CAS: 108608-25-9), Triethylammonium carbadodecaborate (CAS: 223548-06-9), and Sodium carbadodecaborate (CAS: 92468-38-7), represent a unique class of boron cluster materials combining ionic character with exceptional robustness.

These salts contain the [CB11H12]⁻ anion, one of the most stable and weakly coordinating anions known in chemistry. Their high chemical inertness, low nucleophilicity, and superior resistance to oxidation and hydrolysis make them invaluable in a wide range of applications. In catalysis, carbadodecaborate salts are used as counterions for generating highly active cationic metal complexes, facilitating polymerization, hydrosilylation, and electrophilic substitution reactions.

In electrochemistry and materials science, these compounds serve as electrolytes and ionic liquid components where stability under extreme conditions is crucial. Their compatibility with various solvents and ability to stabilize reactive cations make them attractive for designing functional materials and ionic systems.

Moreover, Sodium carbadodecaborate is frequently utilized in the synthesis of metal–carborane complexes and as a precursor for boron-containing polymers and coatings. Trimethylammonium and Triethylammonium carbadodecaborate salts, in particular, are valued for their solubility and ease of handling in organic media, expanding their usability in both laboratory research and industrial production.

UCHEM ensures a reliable supply of these carbadodecaborate salts with high purity and consistent quality. Each compound undergoes strict analytical verification, supporting research in organometallic catalysis, advanced materials, and boron chemistry.

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Last Update : 29 October 2025 7:05 AM
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Item  Owner  : Nina He
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